Press Releases / Pressemitteilungen

The advantageous properties of metal halide perovskites include their high light-harvesting capacity and their remarkable ability to efficiently convert solar energy into electrical energy. Another special feature of these materials is that both charge carriers and ions are mobile within them. While charge carrier transport is a fundamental process required for the photovoltaic operation of the solar cell, ionic defects and ion transport often have undesirable consequences on the performance of these devices. Despite significant progress in this field of research, many questions regarding the physics of ions in perovskite materials remain open.

On the way to a better understanding of these structures, the Technical Universities of Chemnitz and Dresden have now taken a big step forward. In a joint investigation by the research groups around Prof. Dr. Yana Vaynzof (Chair of Emerging Electronic Technologies at the Institute of Applied Physics and Center for Advancing Electronics Dresden – cfaed, TU Dresden) and Prof. Dr. Carsten Deibel (Optics and Photonics of Condensed Matter, Chemnitz University of Technology) under the leadership of Chemnitz University of Technology, the two teams uncovered the ionic defect landscape in metal halide perovskites. They were able to identify essential properties of the ions that make up these materials. The migration of the ions leads to the presence of defects in the material, which have a negative effect on the efficiency and stability of perovskite solar cells. The working groups found that the motion of all observed ions, despite their different properties (such as positive or negative charge), follows a common transport mechanism and also allows the assignment of defects and ions. This is known as the Meyer-Neldel rule. The results were published in the renowned journal "Nature Communications" (11, 6098 (2020)) (https://www.nature.com/articles/s41467-020-19769-8).

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